The Second Law: An Introduction to Classical and Statistical ThermodynamicsOxford University Press, 1965 - 429 pàgines |
Continguts
Introduction and Synopsis | 1 |
The First Law I | 9 |
The Second Law I | 25 |
Survey of Molar Entropies 1 | 35 |
Raising and Lowering Weights Reversibly | 52 |
Melting and Freezing | 64 |
Free Expansion of an Ideal Gas | 72 |
Chemical Equilibrium I | 84 |
Einsteins Solid | 155 |
Boltzmanns Factor and Partition Functions | 163 |
Configurational Entropy | 179 |
ElectronTransfer Reactions and Galvanic Cells I | 195 |
ProtonTransfer Reactions and pH | 212 |
Configurational Entropy and Colligative Properties | 229 |
Temperature 1 43 | 230 |
Concluding Comments | 245 |
Chemical Equilibrium II | 92 |
Addendum to Part I | 102 |
Introduction and Review | 113 |
Free Energy Functions and Phase Diagrams | 122 |
Free Energy Curves and Phase Transitions | 128 |
An Introduction to Statistical Thermodynamics | 135 |
Statistical Mechanics of Very Small Systems | 144 |
Thermodynamics of Rubber Elasticity | 258 |
Algebraic Method for Obtaining Thermodynamic Formulas | 266 |
Lagranges Multipliers | 283 |
Additional Problems | 380 |
Bibliography | 393 |
Physical Constants Numerical Factors | 416 |
Altres edicions - Mostra-ho tot
The Second Law: An Introduction to Classical and Statistical Thermodynamics Henry A. Bent Visualització de fragments - 1965 |
The Second Law: An Introduction to Classical and Statistical Thermodynamics Henry A. Bent Visualització de fragments - 1965 |
The Second Law: An Introduction to Classical and Statistical Thermodynamics Henry A. Bent Visualització de fragments - 1965 |
Frases i termes més freqüents
absolute temperature acid adiabatic AEwt aragonite AStotal atoms Boltzmann's cal/deg cal/deg-mole cal/mole calculated calories chemical system concentration configurational entropy constant volume decreases dissociation electron energy change energy levels enthalpy entropy change equal equation equilibrium constant equilibrium with respect escaping tendency example excited expression free energy free energy curve freezing gases H₂O H₂O(liq H₂O+ H3O+ heat capacity heat engine high temperatures hydrochloric acid hydrogen ideal gas increases ions isothermal expansion liquid phase liquid water logarithm low temperatures mechanical microstates molar entropy molar free energy mole molecules monoclinic motion n₁ N₂ occur oscillators oxygen partial pressure particles potential energy Problems for Chapter produced protons quantity Raoult's Law reactants reaction H₂ reversible Second Law solid solution solvent spontaneously substance substance's T₁ T₂ term thermal energy thermal surroundings thermodynamic total entropy universe V₁ vapor pressure vibrational weight zero ΔΕ ΔΗ