Amino Acids and the Asymmetry of Life: Caught in the Act of Formation"How did life originate and why were left-handed molecules selected for its architecture?" This question of high public and interdisciplinary scientific interest is the central theme of this book. It is widely known that in processes triggering the origin of life on Earth, the equal occurrence, the parity between left-handed amino acids and their right-handed mirror images, was violated. The balance was inevitably tipped to the left – as a result of which life's proteins today exclusively implement the left form of amino acids. Written in an engaging style, this book describes how the basic building blocks of life, the amino acids, formed. After a comprehensible introduction to stereochemistry, the author addresses the inherent property of amino acids in living organisms, namely the preference for left-handedness. What was the cause for the violation of parity of amino acids in the emergence of life on Earth? All the fascinating models proposed by physicists, chemists and biologist are vividly presented including the scientific conflicts. The author describes the attempt to verify any of those models with the chirality module of the ROSETTA mission, a probe built and launched with the mission to land on a comet and analyse whether there are chiral organic compounds that could have been brought to the Earth by cometary impacts. A truly interdisciplinary astrobiology book, "Amino Acids and the Asymmetry of Life" will fascinate students, researchers and all readers with backgrounds in natural sciences. With a foreword by Henri B. Kagan. |
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He introduced me to the intriguing field of chirality, to theories on the origin of biomolecular asymmetry, ... effects with Laurence Barron, University of Glasgow, and Geert Rikken, Grenoble High Magnetic Field Laboratory.
... polarized light b 0 Helical term in Moffit-Young equation B Magnetic field vector BZ Belousov-Zhabotinskii C 1 Non-axial point group CD Circular dichroism and cyclodextrin CG Comet 67P/Churyumov-Gerasimenko Unit-system based on cm, ...
1998 Asymmetric ß-decay Parity Violation by Weak Force Kuhn & Braun 1929 Rikken & Raupach 2000 - Circular polarized electromagnetic radiation - Magnetic fields Chiral Fields determinated processes Origin of a chiral bias Origin of Life ...
1.3.2.1 Magneto-Optical Effects Oriented magnetic fields have been suggested as physical driving forces, capable of inducing enantioenrichments into racemic or prochiral organic molecules. Here, the direction of the magnetic field ...
Ph.D. student Guido Zadel performed an enantioselective reaction in a static magnetic field at the University of Bonn. Chiral arylethanols were synthesized starting from prochiral ketones. The resulting enantiomeric excess (20–98%) of ...
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Continguts
Stereochemistry for the Study of the Origin of Life | 17 |
3 | 42 |
When Crystals Deliver Chirality to Life | 61 |
The Weak Nuclear Interaction | 79 |
Light Magnetism and Chirality | 103 |
Key to the Prebiotic Origin of Amino Acids | 125 |
A New Record for Chiral Molecules in Meteorites 145 | 144 |
Chiral Molecules on Comets and on Mars | 161 |
Amplification Mechanisms 185 | 184 |
Appendix | 199 |
Bibliography | 207 |
Index | 229 |
Altres edicions - Mostra-ho tot
Amino Acids and the Asymmetry of Life: Caught in the Act of Formation Uwe Meierhenrich Previsualització no disponible - 2010 |
Amino Acids and the Asymmetry of Life: Caught in the Act of Formation Uwe Meierhenrich Previsualització no disponible - 2008 |
Amino Acids and the Asymmetry of Life: Caught in the Act of Formation Uwe Meierhenrich Previsualització no disponible - 2008 |