The Physical Chemistry of SolidsAcademic Press, 1992 - 584 pàgines The Physical Chemistry of Solids represents an integrated textbooks on solid state chemistry at an introductory level. This text book will provide instructors with the opportunity to develop a unified course on solid state chemistry at the upper undergraduate/lower graduate level. All major aspects of solid state chemistry are covered as are the principles of chemical bonding and related mathematical concepts and operations. The book concludes each chapter with problem sets to facilitate teaching or self study. |
Continguts
Chapter | 1 |
Lattices | 10 |
Covalently Bonded Elements | 25 |
Space Groups | 30 |
The Unit Cell | 36 |
Chapter 3 | 61 |
Exercises | 62 |
Crystal Structures of | 63 |
Metallic Compounds | 320 |
Exercises | 321 |
Chapter 9 | 322 |
Polyphase Equilibrium | 323 |
The LiquidSolid Phase Diagram for Ideal Binary Solutions | 327 |
Nonideal Solutions | 331 |
Phase Separation | 335 |
Equilibrium Among Phases | 336 |
Appendix C | 66 |
The Einstein Heat Capacity | 72 |
37 | 76 |
69 | 84 |
Thermodynamic Functions | 89 |
Potential Functions | 90 |
Chapter 5 | 117 |
The Repulsive Potential | 124 |
The BornHaber Cycle | 130 |
Entropies of Solid Compounds | 138 |
Ionic Packing and Crystal Structure | 148 |
Ionic Bonds | 154 |
Exercises | 176 |
Equations of State | 178 |
Chapter 6 | 179 |
Atomic Wave Functions | 189 |
The Effect of Pressure on Heat Capacity | 190 |
The Covalent Bond | 195 |
48 | 197 |
Ligand Fields | 214 |
Exercises | 225 |
Additional Reading | 226 |
Chapter 7 | 227 |
Covalent Crystals | 229 |
The Silicates | 232 |
Silicate Minerals | 243 |
B ClosePacked Structures | 249 |
Thermodynamics of Semiconduction | 250 |
Electrons in a Periodic Potential | 255 |
The FaceCentered Cubic | 268 |
Elemental Intrinsic Semiconductors | 269 |
Compound Semiconductors | 270 |
Extrinsic Semiconductors | 273 |
Graphite | 274 |
Intercalate Compounds | 276 |
ElectronDeficient Elements and Compounds | 280 |
Exercises | 284 |
Chapter 8 | 285 |
Metallic Crystals | 287 |
The Band Model | 288 |
The Metallic Bond | 290 |
The Hexagonal Structure | 298 |
The Pseudopotential | 299 |
Metallic Solid Solutions | 302 |
Intermediate Phases | 305 |
The Phase Rule | 339 |
Phase Diagram for SingleComponent Systems | 340 |
Binary Phase DiagramsConstruction and Nomenclature | 345 |
The Lever Law | 349 |
Eutectics | 350 |
Complex Phase Reactions | 353 |
FreeEnergy Diagrams | 355 |
Ternary Systems | 357 |
Exercises | 364 |
Additional Reading | 366 |
Chapter 10 | 367 |
Activities Derived from Phase Diagrams | 370 |
Henrys Law | 372 |
Phase Separation | 376 |
SolidGas Reactions | 378 |
Equilibrium between Compounds and Gases | 381 |
Exercises | 384 |
Additional Reading | 386 |
Chapter 11 | 386 |
The Chemistry of Interfaces | 387 |
Surface Free Energy | 388 |
The Chemical Potential as a Function of Surface Curvature | 390 |
The Gibbs Adsorption Isotherm | 393 |
The Segregation of Impurities at Interfaces | 395 |
The Langmuir Adsorption Isotherm | 397 |
The BET Isotherm | 400 |
The Rate and Mechanism of Thermal Desorption | 403 |
Coupled Adsorption and Bulk Diffusion | 405 |
ChemisorptionChemical Bonding to Surfaces | 408 |
Effects of Surface Structure | 415 |
Surface ReactionsCarbon | 417 |
Exercises | 419 |
Additional Reading | 421 |
Crystal Defects | 423 |
Defect Complexes | 437 |
Chapter 13 | 449 |
Representative Experimental Results | 463 |
Exercises | 484 |
OrderDisorder Transitions | 498 |
Spinodal Decomposition | 518 |
The Photographic Process | 538 |
ZeroPoint Energy of the Harmonic Oscillator | 553 |
Appendix | 569 |
Altres edicions - Mostra-ho tot
The Physical Chemistry of Solids Richard John Borg,George Julian Dienes Previsualització no disponible - 1992 |
Frases i termes més freqüents
adsorbed adsorption alkali anion approximation atomic orbitals atoms Brillouin zone C₁ calculated cations Chapter charge chemical bond Chemistry coefficient component composition compounds concentration conduction band configuration constant coulombic covalent bonds crystal structure cubic defined derived diffusion dipole distance electronegativities electrons electrostatic elements enthalpy entropy equation equilibrium example experimental Figure free energy frequency given graphite halides heat capacity hence hybrid hydrogen illustrated interaction internal energy interstitial ionic bonds ionic crystals ionic radii ions isothermal lattice energy liquid Madelung constant magnetic melting metals molecular molecules N₁ NaCl nearest neighbors obtain octahedral orbitals oxidation parameters perovskites phase diagram Phys plane potential energy potential functions pressure quantum number radius repulsive result Schrödinger equation semiconductors shell shown in Fig solid solutions spin spinel Substituting surface symmetry Table temperature tetrahedral thermal thermodynamic total number unit cell vacancy valence values vibrational wave functions ΔΗ