Crystalline Molecular Complexes and Compounds: Structures and PrinciplesOUP Oxford, 17 de nov. 2005 - 1352 pàgines This book provides a comprehensive and unified account of the structure and properties of crystalline binary adducts. Perhaps better known as molecular complexes and compounds, these crystals are currently estimated (from molecular recognition studies) to make up one quarter of the world's crystals, providing evidence for some sort of special attraction between the two components. DNA is perhaps the most famous example but others (hydrates, solvates, host-guest inclusion complexes, donor-acceptor compounds) pervade the whole body of solid state chemistry. Although much research has been published, there has never been a comprehensive and unified treatment of the whole field. This book has been designed to fill this gap, comparing and contrasting the various examples and the different types of interaction (hydrogen bonding, inclusion and localized or delocalized charge transfer). More than 600 figures, 200 tables and 3500 references are included in the book. Since most 'parent compounds' form a number of adducts, the fraction of crystalline binary adducts is only going to grow making this account just the 'tip of the iceberg'. |
Continguts
| 21 | |
HOSTGUEST INCLUSION COMPLEXES | 197 |
PACKING COMPLEXES | 559 |
MOLECULAR COMPOUNDS WITH LOCALIZED INTERACTIONS | 679 |
MOLECULAR COMPOUNDS WITH DELOCALIZED INTERACTIONS | 919 |
Appendix | 1267 |
| 1275 | |
Altres edicions - Mostra-ho tot
Crystalline Molecular Complexes and Compounds: Structures and Principles Frank H. Herbstein Previsualització limitada - 2005 |
Crystalline Molecular Complexes and Compounds: Structures and ..., Volum 1 Frank H. Herbstein Previsualització limitada - 2005 |
Crystalline Molecular Complexes and Compounds:Structures and Principles ... Frank H. Herbstein Previsualització no disponible - 2005 |
Frases i termes més freqüents
acceptor acid Acta Cryst analogous angles appear aromatic arrangement atoms axis benzene cations cavities cell dimensions centres changes Chapter charge transfer Chem chemical Chemistry clathrate components composition conformation considered containing coordination crystal structure crystallographic described detail determined diffraction dimers discussed disordered distances donor electron et al example formation four framework give given guest guest molecules Herbstein hexagonal host hydrates hydrogen bonds important inclusion complexes interactions intercalation ions isomorphous layers linked measurements metal moieties molecular compounds molecules monoclinic nature noted obtained ordered oxygen packing pairs phase Phys plane polymorphs positions possible prepared racemic range References reported Reproduced ring shown similar single solid solutions space group stability stacks studies symmetry Table temperature triclinic tunnel tunnel inclusion complexes unit cell urea values various viewed volume